Volume 13, Issue 2 (7-2025)                   J Environ Health Eng 2025, 13(2): 189-203 | Back to browse issues page

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Govahi S, Derikvand E, khoshnavaz S, Solimani Babarsad M, Parseh I. Assessment of Greywater Treatment Efficiency Using of Surface Adsorption with Iron oxide nanoparticles. J Environ Health Eng 2025; 13 (2) :189-203
URL: http://jehe.abzums.ac.ir/article-1-1106-en.html
Research Center for Water Science and Environmental, Department of Water Sciences, Sho.C., Islamic Azad University, Shoushtar, Iran , Ehsan.Derikvand@iau.ac.ir
Abstract:   (31 Views)
Background: In recent years, the management and treatment of greywater have become critical environmental challenges due to the presence of non-biodegradable pollutants that conventional wastewater treatment methods fail to fully remove. This study aims to evaluate the efficiency of a hybrid approach combining adsorption using iron oxide nanoparticles (Fe₃O₄) and advanced chemical oxidation with UV/H₂O₂ for greywater treatment.
Materials and Methods: Greywater samples were first treated with Fe₃O₄ nanoparticles under optimized conditions: pH=5, contact time of 40 minutes, and adsorbent dosage of 1.2 g/L. Subsequently, UV/H₂O₂ oxidation was applied to enhance removal efficiency.
Results: Adsorption alone achieved removal efficiencies of 57% for COD, 36% for BOD, 7.5% for TKN, and 60% for TP. Following UV/H₂O₂ oxidation, COD removal increased to over 93%, reducing residual COD to 12.1 mg/L. The process showed optimal performance at lower pH levels 4 to 5, while H₂O₂ concentrations up to 7 mM improved oxidation efficiency without significant enhancement beyond this level.
Conclusion: The integration of physical adsorption and advanced oxidation not only overcomes the limitations of conventional methods but also meets environmental discharge standards. With high efficiency and relatively low operational costs, this dual-stage method offers a sustainable solution for greywater management in urban and industrial settings.
Full-Text [PDF 541 kb]   (24 Downloads)    
Type of Study: Research | Subject: Special
Received: 2025/03/13 | Accepted: 2025/06/7 | Published: 2025/07/16

References
1. Hlongwane GN, Sekoai PT, Meyyappan M, Moothi K. Simultaneous removal of pollutants from water using nanoparticles: a shift from single pollutant control to multiple pollutant control. Sci Total Environ . 2019;656:808-33. [DOI:10.1016/j.scitotenv.2018.11.257]
2. Xu P, Zeng GM, Huang DL, Feng CL, Hu S, Zhao MH, et al. Use of iron oxide nanomaterials in wastewater treatment: a review. Sci Total Environ . 2012;424:1-10. [DOI:10.1016/j.scitotenv.2012.02.023]
3. Gharloghi M, Yazdanbakhsh A, Eslami A, Aghayani E. Efficiency of iron oxide nanoparticles in advanced treatment of secondary effluent of municipal wastewater treatment plant. J Mazandaran Univ Med Sci . 2016;26(135):130-43.
4. Zhang J, Lin S, Han M, Su Q, Xia L, Hui Z. Adsorption properties of magnetic magnetite nanoparticle for coexistent Cr(VI) and Cu(II) in mixed solution. Water (Basel) . 2020;12(2):446. [DOI:10.3390/ma13020446]
5. Predescu AM, Matei E, Berbecaru AC, Pantilimon C, Drăgan C, Vidu R, et al. Synthesis and characterization of dextran-coated iron oxide nanoparticles. R Soc Open Sci . 2018;5(3):171525. [DOI:10.1098/rsos.171525]
6. Shojaei S, Khammarnia S, Shojaei S, Sasani M. Removal of reactive Red 198 by nanoparticle zero valent iron in the presence of hydrogen peroxide. J Water Environ Nanotechnol . 2017;2(2):129-35.
7. Renu, Agarwal M, Singh K. Heavy metal removal from wastewater using various adsorbents: a review. J Water Reuse Desal . 2017;7(4):387-419. [DOI:10.2166/wrd.2016.104]
8. Mohapatra M, Anand S. Synthesis and applications of nano-structured iron oxides/hydroxides - a review. Int J Eng Sci Technol . 2011;2(8):127-46. [DOI:10.4314/ijest.v2i8.63846]
9. Ali A, Zafar H, Zia M, ul Haq I, Phull AR, Ali JS, et al. Synthesis, characterization, applications, and challenges of iron oxide nanoparticles. Nanotechnol Sci Appl . 2016;9:49-67. [DOI:10.2147/NSA.S99986]
10. Zazouli MA, Belarak D, Karimnezhad F, Khosravi F. Removal of fluoride from aqueous solution by using of adsorption onto modified Lemna minor: adsorption isotherm and kinetics study. J Mazandaran Univ Med Sci . 2014;23(109):195-204.
11. Lakshmanan R, Sanchez-Dominguez M, Matutes-Aquino JA, Wennmalm S, Kuttuva Rajarao G. Removal of total organic carbon from sewage wastewater using poly(ethylenimine)-functionalized magnetic nanoparticles. Langmuir . 2014;30(4):1036-44. [DOI:10.1021/la404076n]
12. Drenkova-Tuhtan A, Mandel K, Paulus A, Meyer C, Hutter F, Gellermann C, et al. Phosphate recovery from wastewater using engineered superparamagnetic particles modified with layered double hydroxide ion exchangers. Water Res . 2013;47(15):5670-7. [DOI:10.1016/j.watres.2013.06.039]
13. Consultants I. Code. In: Fire Flow Water Consumption in Sprinklered and Unsprinklered Buildings, An Assessment of Community Impacts. Philadelphia: Springer Science & Business Media; 2012. [DOI:10.1007/978-1-4614-8109-6]
14. Lu AH, Salabas EL, Schüth F. Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angew Chem Int Ed . 2007;46(8):1222-44. [DOI:10.1002/anie.200602866]
15. Hatt BE, Fletcher TD, Deletic A. Treatment performance of gravel filter media: implications for design and application of stormwater infiltration systems. Water Res . 2007;41(12):2513-24. [DOI:10.1016/j.watres.2007.03.014]
16. Rahmani AR, Ghafari HR, Samadi MT, Zarabi M. Synthesis of zero valent iron nanoparticles (nzvi) and its efficiency in arsenic removal from aqueous solutions. Water Wastewater . 2011;1:35-41.

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