دوره 13، شماره 4 - ( 12-1404 )                   جلد 13 شماره 4 صفحات 436-412 | برگشت به فهرست نسخه ها

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Keramatzadeh M, Takdastan A, Ehteshami M. Systematic Review on the Application of Biomass-Derived Biochars for the Removal of 2,4-Dichlorophenoxyacetic Acid from Agricultural Water Sources. J Environ Health Eng 2026; 13 (4) :412-436
URL: http://jehe.abzums.ac.ir/article-1-1135-fa.html
کرامت زاده مژده، تکدستان افشین، احتشامی مجید. مرور نظام‌مند بر کاربرد بایوچارهای مشتق‌شده از زیست‌توده در حذف علف‌کش 2و4-دی کلروفنوکسی استیک اسید از منابع آبی کشاورزی. مجله مهندسی بهداشت محیط. 1404; 13 (4) :412-436

URL: http://jehe.abzums.ac.ir/article-1-1135-fa.html


1- دانشکده مهندسی عمران، دانشگاه صنعتی خواجه نصیرالدین طوسی، تهران، ایران
2- مرکز تحقیقات فناوری‌های زیست‌محیطی، دانشگاه علوم پزشکی جندی‌شاپور اهواز، اهواز، ایران ، afshin_ir@yahoo.com
چکیده:   (24 مشاهده)
زمینه و هدف: آلودگی منابع آب با علف‌کش 2و4-دی از مهم‌ترین چالش‌های زیست‌محیطی به شمار می‌رود، زیرا بقایای آن علاوه بر تأثیر بر کیفیت آب آشامیدنی، سلامت اکوسیستم‌های آبی و زنجیره غذایی را تهدید می‌کند. هدف این مطالعه، مرور نظام‌مند پژوهش‌های انجام‌شده درباره کارایی انواع بایوچار در حذف این ترکیب مقاوم از محیط‌های آبی است.
مواد و روش‌ها: این مطالعه با جستجو و تحلیل نظام‌مند منابع علمی منتشرشده در زمینه استفاده از بایوچار برای جذب سطحی 2و4-دی در پایگاه‌های Web of Science، Scopus، ScienceDirect و Google Scholar بر اساس دستورالعمل PRISMA انجام شد. بازه زمانی جستجو سال‌های ۲۰۰۸ تا ۲۰۲۵ بود و مقالات بر اساس نوع پیش‌ماده، شرایط پیرولیز، روش اصلاح و فعال‌سازی و پارامترهای مؤثر بر فرآیند جذب ارزیابی شدند.
یافته‌ها: مرور مطالعات نشان داد ظرفیت جذب بایوچارها دامنه وسیعی دارد و تحت تأثیر نوع زیست‌توده، شرایط پیرولیز و روش‌های اصلاح قرار گرفته است. بیشتر پژوهش‌ها بهترین برازش ایزوترمی و سینتیکی را با مدل‌های لانگمویر و شبه‌مرتبه دوم گزارش کرده‌اند. همچنین شرایط اسیدی (pH =۲–۳) بالاترین راندمان حذف را ایجاد کرده است. با این حال، چالش‌هایی مانند بازیابی جاذب، ارزیابی عملکرد در شرایط واقعی و تأثیر ترکیبات هم‌زمان باقی است.
نتیجه‌گیری: این مطالعه مروری بر لزوم توسعه بایوچارهای حاصل از ضایعات کشاورزی و بهبود ویژگی‌های سطحی آن‌ها تأکید دارد تا زمینه کاربرد صنعتی و پایدار این جاذب‌ها در حذف علف‌کش‌ها، به‌ویژه 2و4-دی، از منابع آب و پساب فراهم شود.
متن کامل [PDF 3153 kb]   (13 دریافت)    
نوع مطالعه: كاربردي | موضوع مقاله: تخصصي
دریافت: 1404/6/27 | پذیرش: 1404/10/15 | انتشار: 1404/12/27

فهرست منابع
1. Islam F, Wang J, Farooq MA, Khan MS, Xu L, Zhu J, Zhao M, Muños S, Li QX, Zhou W. Potential impact of the herbicide 2, 4-dichlorophenoxyacetic acid on human and ecosystems. Environment international. 2018;111:332-351. [DOI:10.1016/j.envint.2017.10.020]
2. Benbrook CM. Trends in glyphosate herbicide use in the United States and globally. Environmental Sciences Europe. 2016;28:3. [DOI:10.1186/s12302-016-0070-0]
3. Gervais J, Luukinen B, Buhl K, Stone D. 2, 4-D technical fact sheet. National Pesticide Information Center, Oregon State University Extension Services. 2008.
4. Ambrus A, Hamilton DJ. Food safety assessment of pesticide residues. World Scientific; 2017. [DOI:10.1142/q0050]
5. Ehteshami M, Keramatzadeh M, Takdastan A. Analysis and Monitoring of the Herbicide 2, 4-D in Agricultural Drainage Systems and Karun River Using HPLC Method. Pollution. 2025;11:889-900.
6. Orooji N, Takdastan A, Jalilzadeh Yengejeh R, Jorfi S, Davami AH. Monitoring of 2, 4-dichlorophenoxyacetic acid concentration in Karun River and effluents of water treatment plants. Toxin Reviews. 2022;41:785-794. [DOI:10.1080/15569543.2021.1929322]
7. Jorfi S, Almasi H, Takdastan A, Jaafarzadeh N, Tahmasebi Y, Babaei A. Spatiotemporal variations of 2, 4-dichlorophenoxy acetic acid with the role of sugarcane industry and related human health risk assessments in the Shadegan International Wetland. Environmental Geochemistry and Health. 2023;45:5279-5291. [DOI:10.1007/s10653-023-01573-0]
8. Shahsavari AA, Khodaei K, Asadian F, Ahmadi F, Zamanzadeh SM. Groundwater pesticides residue in the southwest of Iran-Shushtar plain. Environmental Earth Sciences. 2012;65:231-239. [DOI:10.1007/s12665-011-1086-9]
9. Organization WH. Guidelines for drinking-water quality: incorporating the first and second addenda. World Health Organization; 2022.
10. Jorfi S, Poormohammadi A, Maraghi E, Almasi H. Monitoring and health risk assessment of organochlorine pesticides in Karun River and drinking water Ahvaz city, South West of Iran. Toxin Reviews. 2022;41:361-369. [DOI:10.1080/15569543.2021.1876091]
11. Rezaeigolestani M, Hashemi M. A review of pesticide residues in agricultural and food products of Iran. Journal of nutrition, fasting and health. 2018;6:1-6.
12. Samarghandi MR, Jaafarzadeh Haghighi Fard N, Jorfi S, Yari AR, Panahi Fard M. Pollution status of pesticide residues in food products in Iran: A mini-review within 2008-2018. Archives of Hygiene Sciences. 2020;9:214-223. [DOI:10.29252/ArchHygSci.9.3.214]
13. Meftaul IM, Venkateswarlu K, Dharmarajan R, Annamalai P, Megharaj M. Movement and fate of 2, 4-D in urban soils: A potential environmental health concern. ACS omega. 2020;5:13287-13295. [DOI:10.1021/acsomega.0c01330]
14. Buerge IJ, Pavlova P, Hanke I, Bächli A, Poiger T. Degradation and sorption of the herbicides 2, 4-D and quizalofop-P-ethyl and their metabolites in soils from railway tracks. Environmental Sciences Europe. 2020;32:150. [DOI:10.1186/s12302-020-00422-6]
15. Parven A, Md Meftaul I, Venkateswarlu K, Gopalan S, Megharaj M. Pre-emergence herbicides widely used in urban and farmland soils: fate, and potential human and environmental health risks. Environmental Geochemistry and Health. 2024;46:132. [DOI:10.1007/s10653-024-01907-6]
16. Wozniak-Karczewska M, Parus A, Ciesielski T, Trzebny A, Szumski R, Wilms W, Homa J, Framski G, Baranowski D, Frankowski R. Effect of cation sorption on 2, 4-D mobility of herbicidal ionic liquids in agricultural soil combined with diversity of the bacterial community. ACS Sustainable Chemistry & Engineering. 2022;10:12559-12568. [DOI:10.1021/acssuschemeng.2c02665]
17. Freisthler MS, Robbins CR, Benbrook CM, Young HA, Haas DM, 17- Winchester PD, Perry MJ. Association between increasing agricultural use of 2, 4-D and population biomarkers of exposure: findings from the National Health and Nutrition Examination Survey, 2001-2014. Environmental Health. 2022;21:23. [DOI:10.1186/s12940-021-00815-x]
18. Parven A, Meftaul IM, Venkateswarlu K, Megharaj M. Herbicides in modern sustainable agriculture: environmental fate, ecological implications, and human health concerns. International Journal of Environmental Science and Technology. 2025;22:1181-1202. [DOI:10.1007/s13762-024-05818-y]
19. Mekonen S, Argaw R, Simanesew A, Houbraken M, Senaeve D, Ambelu A, Spanoghe P. Pesticide residues in drinking water and associated risk to consumers in Ethiopia. Chemosphere. 2016;162:252-260. [DOI:10.1016/j.chemosphere.2016.07.096]
20. Burns C, Bodner K, Swaen G, Collins J, Beard K, Lee M. Cancer incidence of 2, 4-D production workers. International Journal of Environmental Research and Public Health. 2011;8:3579-3590. [DOI:10.3390/ijerph8093579]
21. Burns CJ, Swaen GM. Review of 2, 4-dichlorophenoxyacetic acid (2, 4-D) biomonitoring and epidemiology. Critical Reviews in Toxicology. 2012;768:42-786. [DOI:10.3109/10408444.2012.710576]
22. Dann AB. The effects of triclosan, 2, 4-D, and their by-products on the adrenocortical cells of rainbow trout. In: Lethbridge, Alta.: University of Lethbridge, Dept. of Biological Sciences, c2011; 2011.
23. Curi LM, Peltzer P, Sandoval MT, Lajmanovich RC. Acute toxicity and sublethal effects caused by a commercial herbicide formulated with 2, 4-D on Physalaemus albonotatus tadpoles. Water, Air, & Soil Pollution. 2019;230:22. [DOI:10.1007/s11270-018-4073-x]
24. Gaaied S, Oliveira M, Domingues I, Banni M. 2, 4-Dichlorophenoxyacetic acid herbicide effects on zebrafish larvae: development, neurotransmission and behavior as sensitive endpoints. Environmental Science and Pollution Research. 2020;27:3686-3696. [DOI:10.1007/s11356-019-04488-5]
25. Viriato C, Franca FM, Santos DS, Marcantonio AS, Badaro-Pedroso C, Ferreira CM. Evaluation of the potential teratogenic and toxic effect of the herbicide 2,4-D (DMA® 806) in bullfrog embryos and tadpoles (Lithobates catesbeianus). Chemosphere. 2021;266:129018. [DOI:10.1016/j.chemosphere.2020.129018]
26. Organization WH. Pesticide residues in food-Evaluation 2019: Part II, Toxicological. Food & Agriculture Org.; 2021.
27. Pest HTIY, Pesticides L-R, Poisonings H, Land IOT. 2, 4-D Fact Sheet.
28. National Family Farm Coalition v. US EPA. In: F. 3d. Court of Appeals, 9th Circuit; 2020:893.
29. Girón-Navarro R, Linares-Hernández I, Teutli-Sequeira EA, Martínez-Miranda V, Santoyo-Tepole F. Evaluation and comparison of advanced oxidation processes for the degradation of 2,4-dichlorophenoxyacetic acid (2,4-D): a review. Environmental Science and Pollution Research. 2021;28:26325-26358. [DOI:10.1007/s11356-021-13730-y]
30. Khader EH, Muslim SA, Saady NMC, Ali NS, Salih IK, Mohammed TJ, Albayati TM, Zendehboudi S. Recent advances in photocatalytic advanced oxidation processes for organic compound degradation: A review. Desalination and Water Treatment. 2024;318:100384. [DOI:10.1016/j.dwt.2024.100384]
31. de Souza TF, Dias Ferreira GM. Biochars as Adsorbents of Pesticides: Laboratory-Scale Performances and Real-World Contexts, Challenges, and Prospects. ACS ES&T Water. 2024;4:4264-4282. [DOI:10.1021/acsestwater.4c00399]
32. Satyam S, Patra S. Innovations and challenges in adsorption-based wastewater remediation: A comprehensive review. Heliyon. 2024;10. [DOI:10.1016/j.heliyon.2024.e29573]
33. Ighalo JO, Ojukwu VE, Umeh CT, Aniagor CO, Chinyelu CE, Ajala OJ, Dulta K, Adeola AO, Rangabhashiyam S. Recent advances in the adsorptive removal of 2, 4-dichlorophenoxyacetic acid from water. Journal of Water Process Engineering. 2023;56:104514. [DOI:10.1016/j.jwpe.2023.104514]
34. Gao Y, Zhang Y, Li A, Zhang L. Facile synthesis of high-surface area mesoporous biochar for energy storage via in-situ template strategy. Materials Letters. 2018;230:183-186. [DOI:10.1016/j.matlet.2018.07.106]
35. Flafel HM, Rafatullah M, Lalung J, Kapoor RT, Siddiqui MR, Qutob M. Enhancing the efficiency of phytoremediation using water hyacinth (Eichhornia crassipes) for 2,4-dichlorophenoxyacetic acid removal with modified biochar as an assisted agent. Chemosphere. 2024;367:143591. doi: [DOI:10.1016/j.chemosphere.2024.143591]
36. Zhong Y, Deng Q, Zhang P, Wang J, Wang R, Zeng Z, Deng S. Sulfonic acid functionalized hydrophobic mesoporous biochar: Design, preparation and acid-catalytic properties. Fuel. 2019;240:270-277. [DOI:10.1016/j.fuel.2018.11.152]
37. Yang H, Chen P, Chen W, Li K, Xia M, Xiao H, Chen X, Chen Y, Wang X, Chen H. Insight into the formation mechanism of N, P co-doped mesoporous biochar from H3PO4 activation and NH3 modification of biomass. Fuel Processing Technology. 2022;230:107215. [DOI:10.1016/j.fuproc.2022.107215]
38. Reguyal F, Praneeth S, Sarmah AK. Modelling and spectroscopic investigation of 2, 4-D adsorption in soil amended with pine sawdust, paunch grass and sewage sludge biochars. Water Emerging Contaminants & Nanoplastics. 2023;2:N/A-N/A. [DOI:10.20517/wecn.2023.35]
39. Dong X, Chu Y, Tong Z, Sun M, Meng D, Yi X, Gao T, Wang M, Duan J. Mechanisms of adsorption and functionalization of biochar for pesticides: A review. Ecotoxicology and Environmental Safety. 2024;272:116019. [DOI:10.1016/j.ecoenv.2024.116019]
40. Fernandez ME, del Rosario Morel M, Clebot AC, Zalazar CS, de los Milagros Ballari M. Effectiveness of a simple biomixture for the adsorption and elimination of 2, 4-dichlorophenoxyacetic acid (2, 4-D) herbicide and its metabolite, 2, 4-dichlorophenol (2,4-DCP), for a biobed system. Journal of Environmental Chemical Engineering. 2022;10:106877. [DOI:10.1016/j.jece.2021.106877]
41. Tuzimski T. Pesticide Classification and Properties. In: High Performance Liquid Chromatography in Pesticide Residue Analysis. CRC Press; 2015:11-75. [DOI:10.1201/b18481-4]
42. Peterson MA, McMaster SA, Riechers DE, Skelton J, Stahlman PW. 2, 4-D past, present, and future: a review. Weed Technology. 2016;30:303-345. [DOI:10.1614/WT-D-15-00131.1]
43. Qurratu A, Reehan A. A review of 2, 4-Dichlorophenoxyacetic acid (2, 4-D) derivatives: 2,4-D dimethylamine salt and 2, 4-D butyl ester. International Journal of Applied Engineering Research. 2016;11:9946-9955.
44. University of Hertfordshire AERUA. PPDB: Pesticide Properties Database - 2,4-D. https://sitem.herts.ac.uk/aeru/ppdb/en/Reports/4.htm?utm. 2025.
45. (ATSDR) AfTSaDR. Toxicological profile for 2,4-Dichlorophenoxyacetic acid (2,4-D). In; 2020.
46. (FAO) FaAOotUN. Physico-chemical properties of pure 2,4-D. In; 2021.
47. Canada H. Guidelines for Canadian Drinking Water Quality: Guideline Technical Document 2,4-Dichlorophenoxyacetic acid (2,4-D). In; 2022.
48. Tayeb W, Chaieb I, Hammami M. Environmental fate and effects of 2, 4-dichlorophenoxyacetic herbicide. In: Nova Sciences Publisher: New York; 2011:161-187.
49. Magnoli K, Carranza CS, Aluffi ME, Magnoli CE, Barberis CL. Herbicides based on 2,4-D: its behavior in agricultural environments and microbial biodegradation aspects. A review. Environmental Science and Pollution Research. 2020;27:38501-38512. [DOI:10.1007/s11356-020-10370-6]
50. Wang Y, Tian Y-S, Gao J-J, Xu J, Li Z-J, Fu X-Y, Han H-J, Wang L-J, Zhang W-H, Deng Y-D. Complete biodegradation of the oldest organic herbicide 2,4-Dichlorophenoxyacetic acid by engineering Escherichia coli. Journal of Hazardous Materials. 2023;451:131099. [DOI:10.1016/j.jhazmat.2023.131099]
51. Barros do Nascimento AC, Nhampossa NA, Félix TsP, Itabaiana Jr I, Nascimento RPd. Exploring Fungal Biodegradation Pathways of 2,4-D: Enzymatic Mechanisms, Synergistic Actions, and Environmental Applications. ACS Omega. 2025. [DOI:10.1021/acsomega.5c05161]
52. Vázquez AEG, Chou MY, Hockemeyer KR, Vang M, Koch PL. Seasonal Environmental Variation Impacts 2,4-D Fate and Metabolism in Urban Landscapes. Environmental Toxicology and Chemistry. 2025:vgaf205.
53. Jote CA. A review of 2, 4-D environmental fate, persistence and toxicity effects on living organisms. Org Med Chem Int J. 2019;9:22-32. [DOI:10.19080/OMCIJ.2019.08.555755]
54. Authority EFS, Álvarez F, Arena M, Auteri D, Leite SB, Binaglia M, Castoldi AF, Chiusolo A, Colagiorgi A, Colas M. Updated peer review of the pesticide risk assessment of the active substance dichlorprop‐P and variant dichlorprop‐P‐2‐ethylhexyl. EFSA Journal. 2024;22:e8658. [DOI:10.2903/j.efsa.2024.8658]
55. Mount CRMR. Herbicide systemb.
56. Dehghani M, Nasseri S, Karamimanesh M. Removal of 2, 4-Dichlorophenolyxacetic acid (2, 4-D) herbicide in the aqueous phase using modified granular activated carbon. Journal of Environmental Health Science and Engineering. 2014;12:28. [DOI:10.1186/2052-336X-12-28]
57. Coelho ERC, Brito GMd, Frasson Loureiro L, Schettino Jr MA, Freitas JCCd. 2, 4-dichlorophenoxyacetic acid (2, 4-D) micropollutant herbicide removing from water using granular and powdered activated carbons: a comparison applied for water treatment and health safety. Journal of Environmental Science and Health, Part B. 2020;55:361-375. [DOI:10.1080/03601234.2019.1705113]
58. Sarker A, Kim D, Jeong W-T. Environmental fate and sustainable management of pesticides in soils: a critical review focusing on sustainable agriculture. Sustainability. 2024;16:10741. [DOI:10.3390/su162310741]
59. Ray S, Shaju ST. Bioaccumulation of pesticides in fish resulting toxicities in humans through food chain and forensic aspects. Environmental Analysis, Health and Toxicology. 2023;38:e2023017. [DOI:10.5620/eaht.2023017]
60. Tyohemba RL, Pillay L, Humphries MS. Bioaccumulation of current-use herbicides in fish from a global biodiversity hotspot: Lake St Lucia, South Africa. Chemosphere. 2021;284:131407. [DOI:10.1016/j.chemosphere.2021.131407]
61. Banaee M. Toxicological interaction effects of herbicides and the environmental pollutants on aquatic organisms. In: New Insights in Herbicide Science. IntechOpen; 2022. [DOI:10.5772/intechopen.105843]
62. Hongoeb J, Tantimongcolwat T, Ayimbila F, Ruankham W, Phopin K. Herbicide-related health risks: key mechanisms and a guide to mitigation strategies. Journal of Occupational Medicine and Toxicology. 2025;20:6. [DOI:10.1186/s12995-025-00448-7]
63. (IARC) IAfRoC. IARC Monographs evaluate DDT, lindane, and 2,4‑D (Press Release No 236). In; 2015.
64. Mohd Ghazi R, Nik Yusoff NR, Abdul Halim NS, Wahab IRA, Ab Latif N, Hasmoni SH, Ahmad Zaini MA, Zakaria ZA. Health effects of herbicides and its current removal strategies. Bioengineered. 2023;14:2259526. [DOI:10.1080/21655979.2023.2259526]
65. Gurav R, Mandal S, Smith LM, Shi SQ, Hwang S. The potential of self-activated carbon for adsorptive removal of toxic phenoxyacetic acid herbicide from water. Chemosphere. 2023;339:139715. [DOI:10.1016/j.chemosphere.2023.139715]
66. Chen S-F, Chen W-J, Song H, Liu M, Mishra S, Ghorab MA, Chen S, Chang C. Microorganism-driven 2, 4-D biodegradation: Current status and emerging opportunities. Molecules. 2024;29:3869. [DOI:10.3390/molecules29163869]
67. Wu X, Wang W, Liu J, Pan D, Tu X, Lv P, Wang Y, Cao H, Wang Y, Hua R. Rapid biodegradation of the herbicide 2, 4-dichlorophenoxyacetic acid by Cupriavidus gilardii T-1. Journal of Agricultural and Food Chemistry. 2017;65:3711-3720. [DOI:10.1021/acs.jafc.7b00544]
68. Hosseini N, Toosi MR. Removal of 2,4-D, glyphosate, trifluralin, and butachlor herbicides from water by polysulfone membranes mixed by graphene oxide/TiO2 nanocomposite: study of filtration and batch adsorption. Journal of Environmental Health Science and Engineering. 2019;17:247-258. [DOI:10.1007/s40201-019-00344-3]
69. Gong W, Bai L, Liang H. Membrane-based technologies for removing emerging contaminants in urban water systems: Limitations, successes, and future improvements. Desalination. 2024;590:117974. [DOI:10.1016/j.desal.2024.117974]
70. Blachnio M, Kusmierek K, Swiatkowski A, Derylo-Marczewska A. Adsorption of phenoxyacetic herbicides from water on carbonaceous and non-carbonaceous adsorbents. Molecules. 2023;28:5404. [DOI:10.3390/molecules28145404]
71. Gallego-Ramírez C, Chica E, Rubio-Clemente A. Combination of Biochar and Advanced Oxidation Processes for the Sustainable Elimination of Pharmaceuticals in Water. Sustainability. 2024;16:10761. [DOI:10.3390/su162310761]
72. Ahmed MB, Zhou JL, Ngo HH, Guo W. Adsorptive removal of antibiotics from water and wastewater: progress and challenges. Science of the Total Environment. 2015;532:112-126. [DOI:10.1016/j.scitotenv.2015.05.130]
73. Alluhaybi AA, Alharbi A, Alshammari KF, El-Desouky MG. Efficient adsorption and removal of the herbicide 2,4-dichlorophenylacetic acid from aqueous solutions using MIL-88 (Fe)-NH2. ACS omega. 2023;8:40775-40784. [DOI:10.1021/acsomega.3c05818]
74. Wang Y, Chen L, Zhu Y, Fang W, Tan Y, He Z, Liao H. Research status, trends, and mechanisms of biochar adsorption for wastewater treatment: a scientometric review. Environmental Sciences Europe. 2024;36:25. [DOI:10.1186/s12302-024-00859-z]
75. Jha S, Gaur R, Shahabuddin S, Tyagi I. Biochar as sustainable alternative and green adsorbent for the remediation of noxious pollutants: a comprehensive review. Toxics. 2023;11:117. [DOI:10.3390/toxics11020117]
76. Al-Ghouti MA, Al-Absi RS. Mechanistic understanding of the adsorption and thermodynamic aspects of cationic methylene blue dye onto cellulosic olive stones biomass from wastewater. Scientific Reports. 2020;10:15928. [DOI:10.1038/s41598-020-72996-3]
77. Jagadeesh N, Sundaram B. Adsorption of pollutants from wastewater by biochar: a review. Journal of Hazardous Materials Advances. 2023;9:100-226. [DOI:10.1016/j.hazadv.2022.100226]
78. Samanth A, Chandrasekar R, Vinayagam R, Selvaraj R. Density Functional Theory Insights into the Adsorption of 2, 4-Dichlorophenoxyacetic Acid by Mesoporous Biochar. South African Journal of Chemical Engineering. 2025. [DOI:10.1016/j.sajce.2025.07.004]
79. Lehmann J, Joseph S. Biochar for environmental management: science and technology. Routledge; 2012. [DOI:10.4324/9781849770552]
80. Ahmad M, Rajapaksha AU, Lim JE, Zhang M, Bolan N, Mohan D, Vithanage M, Lee SS, Ok YS. Biochar as a sorbent for contaminant management in soil and water: a review. Chemosphere. 2014;99:19-33. [DOI:10.1016/j.chemosphere.2013.10.071]
81. Braghiroli FL, Bouafif H, Neculita CM, Koubaa A. Activated biochar as an effective sorbent for organic and inorganic contaminants in water. Water, Air, & Soil Pollution. 2018;229:230. [DOI:10.1007/s11270-018-3889-8]
82. Liu K, He Y, Xu S, Hu L, Luo K, Liu X, Liu M, Zhou X, Bai L. Mechanism of the effect of pH and biochar on the phytotoxicity of the weak acid herbicides imazethapyr and 2,4-D in soil to rice (Oryza sativa) and estimation by chemical methods. Ecotoxicology and Environmental Safety. 2018;161:602-609. [DOI:10.1016/j.ecoenv.2018.05.096]
83. Ma W, Song R, Wang Y, Cui X, Yan Y, Liu Z, Wang X, Gao H, Lua R, Zhou W. Optimized Ginkgo leaf biochar: An efficient adsorbent for 2,4‐D herbicide removal from wastewater. Water Environment Research. 2024;96:e11124. [DOI:10.1002/wer.11124]
84. Qiu M, Liu L, Ling Q, Cai Y, Yu S, Wang S, Fu D, Hu B, Wang X. Biochar for the removal of contaminants from soil and water: a review. Biochar. 2022;4:19. [DOI:10.1007/s42773-022-00146-1]
85. Keramatzadeh M, Ehteshami M, Takdastan A. Removal of 2,4-Dichlorophenoxyacetic Acid Using Activated Dates Seed Biochar: Adsorption Characteristics and Optimization. 2025. [DOI:10.21203/rs.3.rs-6638794/v1]
86. Keramatzadeh M, Ehteshami M, Takdastan A. Efficient removal of 2,4-D using NaOH-activated date seed Biochar with adsorption behavior, kinetic and isotherm modeling, and process optimization. Scientific Reports. 2025. [DOI:10.1038/s41598-025-30144-9]
87. Tan X, Liu Y, Zeng G, Wang X, Hu X, Gu Y, Yang Z. Application of biochar for the removal of pollutants from aqueous solutions. Chemosphere. 2015;125:70-85. [DOI:10.1016/j.chemosphere.2014.12.058]
88. Mia S, Dijkstra FA, Singh B. Aging induced changes in biochar's functionality and adsorption behavior for phosphate and ammonium. Environmental science & technology. 2017;51:8359-8367. [DOI:10.1021/acs.est.7b00647]
89. Zhang H, Chen C, Gray EM, Boyd SE. Effect of feedstock and pyrolysis temperature on properties of biochar governing end use efficacy. Biomass and Bioenergy. 2017;105:136-146. [DOI:10.1016/j.biombioe.2017.06.024]
90. Ok YS, Palansooriya KN, Yuan X, Rinklebe J. Special issue on biochar technologies, production, and environmental applications in Critical Reviews in Environmental Science & Technology during 2017-2021. Critical Reviews in Environmental Science and Technology. 2022;52:3375-3383. [DOI:10.1080/10643389.2021.1990446]
91. Kearns JP, Wellborn L, Summers R, Knappe D. 2,4-D adsorption to biochars: Effect of preparation conditions on equilibrium adsorption capacity and comparison with commercial activated carbon literature data. Water research. 2014;62:20-28. [DOI:10.1016/j.watres.2014.05.023]
92. Hameed B, Salman J, Ahmad A. Adsorption isotherm and kinetic modeling of 2, 4-D pesticide on activated carbon derived from date stones. Journal of hazardous materials. 2009;163:121-126. [DOI:10.1016/j.jhazmat.2008.06.069]
93. Binh QA, Nguyen H-H. Investigation the isotherm and kinetics of adsorption mechanism of herbicide 2, 4-dichlorophenoxyacetic acid (2, 4-D) on corn cob biochar. Bioresource Technology Reports. 2020;11:100520. [DOI:10.1016/j.biteb.2020.100520]
94. Georgin J, Franco DSP, Netto MS, Piccilli DGA, Foletto EL, Dotto GL. Adsorption investigation of 2,4-D herbicide on acid-treated peanut (Arachis hypogaea) skins. Environ Sci Pollut Res Int. 2021;28:36453-36463. [DOI:10.1007/s11356-021-12813-0]
95. Ma W, Fan J, Cui X, Wang Y, Yan Y, Meng Z, Gao H, Lu R, Zhou W. Pyrolyzing spent coffee ground to biochar treated with H3PO4 for the efficient removal of 2, 4-dichlorophenoxyacetic acid herbicide: adsorptive behaviors and mechanism. Journal of Environmental Chemical Engineering. 2023;11:109165. [DOI:10.1016/j.jece.2022.109165]
96. Mandal S, Sarkar B, Igalavithana AD, Ok YS, Yang X, Lombi E, Bolan N. Mechanistic insights of 2, 4-D sorption onto biochar: Influence of feedstock materials and biochar properties. Bioresource technology. 2017;246:160-167. [DOI:10.1016/j.biortech.2017.07.073]
97. Bahrami M, Amiri MJ, Beigzadeh B. Adsorption of 2, 4-dichlorophenoxyacetic acid using rice husk biochar, granular activated carbon, and multi-walled carbon nanotubes in a fixed bed column system. Water Science and Technology. 2018;78:1812-1821. [DOI:10.2166/wst.2018.467]
98. Khan MM, Khan A, Bhatti HN, Zahid M, Alissa S, El-Badry YA, Hussein EE, Iqbal M. Composite of polypyrrole with sugarcane bagasse cellulosic biomass and adsorption efficiency for 2, 4-dicholrophonxy acetic acid in column mode. Journal of Materials Research and Technology. 2021;15:2016-2025. [DOI:10.1016/j.jmrt.2021.09.028]
99. Knani S, Khemis IB, Fuhr ACFP, Lefi N, Mahmoud SA, Dotto GL, Alenazi A, Selmi R. Theoretical modeling of 2, 4-dichlorophenoxyacetic acid on acid-treated peanut skin: microscopic analysis via statistical physics treatment. Scientific Reports. 2025;15:14238. [DOI:10.1038/s41598-025-92567-8]
100. Vinayagam R, Nagendran V, Goveas LC, Narasimhan MK, Varadavenkatesan T, Samanth A, Selvaraj R. Machine learning, conventional and statistical physics modeling of 2, 4-Dichlorophenoxyacetic acid (2, 4-D) herbicide removal using biochar prepared from Vateria indica fruit biomass. Chemosphere. 2024;350:141130. [DOI:10.1016/j.chemosphere.2024.141130]
101. Salman JM, Njoku V, Hameed BH. Adsorption of pesticides from aqueous solution onto banana stalk activated carbon. Chemical engineering journal. 2011;174:41-48. [DOI:10.1016/j.cej.2011.08.026]
102. Essandoh M, Wolgemuth D, Pittman CU, Mohan D, Mlsna T. Phenoxy herbicide removal from aqueous solutions using fast pyrolysis switchgrass biochar. Chemosphere. 2017;174:49-57. doi: [DOI:10.1016/j.chemosphere.2017.01.105]
103. Sellaoui L, Dotto GL, Pereira HA, Vieira Y, dos Reis GS, Oliveira ML, Silva LF, Khan MR, Manoharadas S, Godinho M. Adsorptive properties of the pesticides 2, 4-D, mecoprop, and dicamba on a pinus-based biochar: conventional and statistical physics evaluation. Chemical Engineering Journal. 2023;474:145564. [DOI:10.1016/j.cej.2023.145564]
104. Zhu L, Zhao N, Tong L, Lv Y, Li G. Characterization and evaluation of surface modified materials based on porous biochar and its adsorption properties for 2,4-dichlorophenoxyacetic acid. Chemosphere. 2018;210:734-744. doi: [DOI:10.1016/j.chemosphere.2018.07.090]
105. Evy Alice Abigail M. Biochar-based nanocarriers: fabrication, characterization, and application as 2, 4-dichlorophenoxyacetic acid nanoformulation for sustained release. 3 Biotech. 2019;9:317 [DOI:10.1007/s13205-019-1829-y]
106. Tang L, Chen S, Wang N, Jiang X. Comparative study of adsorption and slow-release performance and mechanism of phosphoric acid and ammonia-modified biochars on 2,4-dichlorophenoxyacetic acid. Separation and Purification Technology. 2025;358:130470. [DOI:10.1016/j.seppur.2024.130470]
107. Wang Z, Ren D, Wu J, Jiang S, Yu H, Cheng Y, Zhang S, Zhang X. Study on adsorption-degradation of 2,4-dichlorophenol by modified biochar immobilized laccase. International Journal of Environmental Science and Technology. 2022;19:1393-1406. [DOI:10.1007/s13762-021-03151-2]
108. Amiri MJ, Roohi R, Arshadi M, Abbaspourrad A. 2, 4-D adsorption from agricultural subsurface drainage by canola stalk-derived activated carbon: insight into the adsorption kinetics models under batch and column conditions. Environmental Science and Pollution Research. 2020;27:16983-16997. [DOI:10.1007/s11356-020-08211-7]
109. Hernandes PT, Franco DS, Georgin J, Salau NP, Dotto GL. Adsorption of atrazine and 2, 4-D pesticides on alternative biochars from cedar bark sawdust (Cedrella fissilis). Environmental Science and Pollution Research. 2022;29:22566-22575. [DOI:10.1007/s11356-021-17590-4]
110. Zhu L, Zhao N, Tong L, Lv Y, Li G. Characterization and evaluation of surface modified materials based on porous biochar and its adsorption properties for 2, 4-dichlorophenoxyacetic acid. Chemosphere. 2018;210:734-744. [DOI:10.1016/j.chemosphere.2018.07.090]
111. Brito GM, Roldi LL, Schetino Jr MÂ, Checon Freitas JC, Cabral Coelho ER. High-performance of activated biocarbon based on agricultural biomass waste applied for 2, 4-D herbicide removing from water: adsorption, kinetic and thermodynamic assessments. Journal of Environmental Science and Health, Part B. 2020;55:767-782. [DOI:10.1080/03601234.2020.1783178]
112. Ying B, Lin G, Jin L, Zhao Y, Zhang T, Tang J. Adsorption and degradation of 2, 4-dichlorophenoxyacetic acid in spiked soil with Fe0 nanoparticles supported by biochar. Acta Agriculturae Scandinavica, Section B-Soil & Plant Science. 2015;65:215-221. [DOI:10.1080/09064710.2014.992939]

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